The name diamond is derived from the ancient Greek ἀδάμας (adámas), "unbreakable, untamed", from (a-), "un-" + δαμάω (damáō), "I overpower, I tame". However, diamonds are thought to have been first recognized and mined in India, where significant alluvial deposits of the stone could then be found many centuries ago along the rivers Penner, Krishna and Godavari. Diamonds have been known in India for at least 3000 years but most likely 6000 years.
Diamonds have been treasured as gemstones since their use as religious icons in ancient Indi. Their usage in engraving tools also dates to early human history. Popularity of diamonds has risen since the 19th century because of increased supply, improved cutting and polishing techniques, growth in the world economy, and innovative and successful advertising campaigns.
In 1813, Humphry Davy used a lens to concentrate the rays of the sun on a diamond in an atmosphere of oxygen, and showed that the only product of the combustion was carbon dioxide, proving that diamond is composed of carbon. Later, he showed that in an atmosphere devoid o oxygen, diamond is converted to graphie.
The most familiar usage of diamonds today is as gemstones used for adornment, a usage which dates back into antiquity. The dispersion of white light into spectral colors, is the primary gemological characteristic of gem diamonds. In the twentieth century, experts in the field of gemology have developed methods of grading diamonds and other gemstones based on the characteristics most important to their value as a gem. Four characteristics, known informally as the four Cs, are now commonly used as the basic descriptors of diamonds: these are carat, cut, color, and clarity.
Diamond is the hardest natural material known, where hardness is defined as resistance to scratching. Diamond has a hardness of 10 (hardest) on Mohs scale of minerAL hardness.Diamond's hardness has been known since antiquity, and is the source of its name.
The hardest natural diamonds in the world are from the Copeton and Bingara fields located in the New England area in New South Wales, Australia. They were called can-ni-fare (cannot be cut) by the cutters in Antwerp when they started to arrive in quantity from Australia in the 1870s. These diamonds are generally small, perfect to semiperfect octahedra, and are used to polish other diamonds. Their hardness is considered to be a product of the crystal growth form, which is single stage growth crystal. Most other diamonds show more evidence of multiple growth stages, which produce inclusions, flaws, and defect planes in the crystal lattice, all of which affect their hardness.
The hardness of diamonds contributes to its suitability as a gemstone. Because it can only be scratched by other diamonds, it maintains its polish extremely well. Unlike many other gems, it is well-suited to daily wear because of its resistance to scratching—perhaps contributing to its popularity as the preferred gem in engagement or wedding rings, which are often worn every day.
Industrial use of diamonds has historically been associated with their hardness; this property makes diamond the ideal material for cutting and grinding tools. As the hardest known naturally occurring material, diamond can be used to polish, cut, or wear away any material, including other diamonds. Common industrial adaptations of this ability include diamond-tipped drill bitsand saws, and the use of diamond powder as an abrasive. Less expensive industrial-grade diamonds, known as bort, with more flaws and poorer color than gems, are used for such purposes.
Diamond is not suitable for machining ferrou alloys at high speeds as carbon is soluble in iron at the high temperatures created by high-speed machining, leading to greatly increased wear on diamond tools when compared to alternatives.
These substances can scratch diamond:
Some diamonds are harder than others.
Nanocrystalline diamond aggregates produced by high-pressure high-temperature treatment of graphite or fullerite (C60).
Borazon - a boron nitride allotrope
Boron nitride
Hexagonal form of diamond called lonsdaleite, is theoretically predicted to be 58% stronger than diamond.
Gem quality diamond may be colorless or occur in any hue including the non-spectral hues of gray, brown and black. Diamond is the only gemstone composed of a single element, carbon. The diamond crystal lattice is exceptionally strong and only atoms of nitrogen, boron, hydrogen, phosphorus and maybe beryllium can be introduced into diamond during the growth at significant concentrations. Transition metals Ni and Co, which are commonly used for growth of synthetic diamond by the high-pressure high-temperature techniques, have been detected in diamond as individual atoms, however the maximum concentration is 0.01% for NiL and even much less for Co. Note however, that virtually any element can be introduced in diamond by ion implantation.
Nitrogen is by far the most common impurity found in gem diamonds. Nitrogen is responsible for the yellow and brown in diamonds. Boron is responsible for the gray blue colors. Color in diamond has two additional sources: irradiation (usually by alpha particles), that causes the color in green diamonds; and physical deformation of the diamond crystal known as plastic deformation. Plastic deformation is the cause of color in some brown and perhaps pink and red diamonds. In order of rarity, colorless diamond, by far the most common, is followed by yellow and brown, by far the most common colors, then by blue, green, black, translucent white, pink, violet, orange, purple, and the rarest, red.[ "Black," or Carbonado, diamonds are not truly black, but rather contain numerous dark inclusions that give the gems their dark appearance. Colored diamonds contain impurities or structural defects that cause the coloration, while pure or nearly pure diamonds are transparent and colorless. Most diamond impurities replace a carbon atom in the crystal lattice, known as a carbon flaw. The most common impurity, nitrogen, causes a slight to intense yellow coloration depending upon the type and concentration of nitrogen present. The Gemological Institute of America (GIA) classifies low saturation yellow and brown diamonds as diamonds in the normal color range, and applies a grading scale from 'D' (colorless) to 'Z' (light yellow). Diamonds of a different color, such as blue, are called fancy colored diamonds, and fall under a different grading scale.
In 2008, the Wittelsbach Diamond, a 35.56 carats (7.11 g) blue diamond once belonging to the King of Spain, fetched over US$24 million at a Christie's auction In 2009 a 7.03 carats (1.41 g) blue diamond fetched the highest price per-carat ever paid for a diamond when it was sold at auction for 10.5 million Swiss francs (6.97 million Euro or US$9.5 million at the time) which is in excess of US$1.3 million per carat.
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